Osha no component of this product present at levels greater than or equal to 0. Calibrate daily with at least six working standards. Toluene, also known as methylbenzene, phenylmethane or toluol is a clear, colorless liquid with a sweet smell. Toluene product safety summary exxonmobil chemical. Eye wash fountains should be provided in the immediate. Toluene diffusive sampler 4000 wikisource, the free. Section 6 accidental release measures general information. Mean blood levels in a nonoccupationally exposed population examined by antoine et al. It is first isolated in 1837 by distillation of pine oil by a polish chemist named filip walter. Hazardous combustion products hazardous decomposition products formed under fire conditions. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. It is also produced in the process of making gasoline and other fuels from crude oil and making coke from coal. It dissolves other substances easily and evaporates quickly into the air.
Identification of the substancemixture and of the companyundertaking. As a msds service provider, we are specialists in ghs. Exposure to benzene, toluene, ethylbenzene, xylene. Show this material safety data sheet to the doctor in attendance. Product identifier product name toluene product number toen reach registration number 012119471051xxxx cas number 108883 eu index number 601021003 ec number 2036259 1. Toluene structure, properties, preparation and reactions. Safety data sheet according to federal register vol. Safety data sheet toluene reference, fuel grade version 1. Acgih no component of this product present at levels greater. Add known amounts of toluene to cs2 in 10ml volumetric flasks and dilute to the mark to produce toluene concentrations in the range 0. Methods for cleaning up use only nonsparking tools. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Transport information land transport us dot no data available. The personal exposure concentrations of benzene, toluene, ethylbenzene, and xylene for a gas station employee were significantly higher than those for indoors and the ambient air.
However, the information is provided without any warranty, express. Toluene is listed in the tsca inventory and in sara 3. Msds authoring services specialize in msds writing, creation, development and authoring. For sampling details, please see the source document.
Exposure controlspersonal protection the use of local exhaust ventilation is recommended to control emissions near the source. Analyze with samples and blanks steps 8 through 10. Material may produce a serious, potentially fatal pneumonia if swallowed or vomited. Disclaimer of liability the information in this msds was obtained from sources which we believe are reliable. Firstaid measures general advice if symptoms persist, call a physician. Bdh180 page 7 of 9 non mutagenic in ames salmonellamicrosome assay non mutagenic in cho chromosome aberration assay other data. Potentially toxicirritating fumesvapors may be evolved. Special protective equipment for firefighters wear self contained breathing apparatus for fire fighting if necessary. Page 1 of 10 safety data sheet toluene diisocyanate.
Signal word danger hazard statements h225 highly flammable liquid and vapour. Toluene occurs naturally in crude oil and in the tolu tree. Reacts chemically with nitrogen oxides, or halogens to form nitrotoluene, nitrobenzene, and. All equipment used when handling the product must be grounded. Studies with laboratory animals 3739 and humans 27 indicate that percutaneous absorption is. Toluene2,4diisocyanate page 3 of 6 good work practices can help to reduce hazardous exposures. Chemical product and company identification product name. Use a noncombustible material like vermiculite, sand or. Use proper personal protective equipment as indicated in section 8. Safety data sheet northwest missouri state university. Product uses toluene is mainly used as a precursor in the production of other chemicals, as a solvent, or as a fuel or fuel additive. Toluene safety data sheet p6240 this sds conforms to u. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication.
It is also used as a precursor for synthesizing benzene. It is colorless, waterinsoluble and has a smell associated with paint thinners. Toluene 1 material safety data sheet sciencelab air. P202 do not handle until all safety precautions have been read and understood. Skin contact wash off immediately with plenty of water for at least 15 minutes. Exposure to toluene can cause eye and nose irritation, tiredness, confusion, euphoria, dizziness, headache, dilated pupils, tears, anxiety, muscle fatigue, insomnia, nerve damage. Other pertinent literature is also presented, but is described in less detail than the key studies. Terminate sampling by sealing the sampler as recommended by the manufacturer or by transferring, in a toluenefree environment, the activated charcoal collection element to a vial and sealing the vial with a septum cap.
The products of degradation are less toxic than the product itself. Toluene was detected in most blood samples of nonoccupationally exposed individuals with a mean level of less than 1 ppb 35. Msds examples sds sheets msds authoring services inc. Toluene2,4diamine was identified but not quantified in wastewater samples from an unspecified industry. Toluene is also called as toluol, is an aromatic hydrocarbon.
Identification of the substancemixture and of the companyundertaking 1. Toluene is added to gasoline, used to produce benzene, and used as a solvent. Prevent exposure to ignition sources, for example use nonsparking tools and explosionproof equipment. Avoid runoff into storm sewers and ditches which lead to waterways. Material safety data sheet information for further. Safety data sheet according to 29cfr19101200 and ghs rev. Toluene can also be used as a recreational inhalant sometimes, and it also has the potential of causing severe neurological harm. Toluene safety in the workplace occupational safety and. Workers whose clothing has been contaminated by toluene2,4diisocyanate should change into clean clothing promptly.
Material safety data sheet toluene, acs 6 cerclasara section 3. Product ingredients section 3 of the msds ingredient cas number proportion toluol 108883 100 for further ingredients information, please refer to the full msds risk phrases section 2 of the msds r 11. Toluene cas no 108883 material safety data sheet sdsmsds. Frozen bromine trifluoride reacts violently with toluene at 80 deg.
Sigmaaldrich 244511 page 3 of 8 suitable extinguishing media use water spray, alcoholresistant foam, dry chemical or carbon dioxide. Absorb spill using an absorbent, noncombustible material such as earth, sand, or vermiculite. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Toluene2,6diisocyanate page 3 of 6 contaminated work clothes should be laundered by individuals who have been informed of the hazards of exposure to toluene2,6diisocyanate. Chronic hydrocarbon abuse for example, sniffing glue or light hydrocarbons such as contained in this material has been associated. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 psm 100x10e12 siemens per meter and is considered a semi conductive. However, we make no warranty of merchantability or any other.
The central nervous system cns is the primary target organ for toluene toxicity in both humans and animals for acute shortterm and chronic longterm exposures. Toluene is also highly flammable and may catch on fire if exposed to heat or flames. Toluene undergoes alkylation in the presence of modified zsm zeolite socony mobil5class zeolite catalysts to form p xylene with high selectivity. In case of skin contact wash off with soap and plenty of water. Exposure to toluene may occur from breathing ambient or indoor air affected by such sources. Toluene is used in making paints, paint thinners, fingernail polish, lacquers, adhesives, and rubber and in. We provide affordable low cost price quotes on quality and accurate msds and ghs services and documents. If inhaled if breathed in, move person into fresh air. Add known amounts of toluene to cs 2 in 10ml volumetric flasks and dilute to the mark to produce toluene concentrations in the range 0. This material is not known or reported to be carcinogenic by any reference source including iarc, osha, ntp, or epa.
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